کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1785501 1023382 2016 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Tailoring structure and magnetic properties of NixCo1−x(N(CN)2)2 molecular magnets
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Tailoring structure and magnetic properties of NixCo1−x(N(CN)2)2 molecular magnets
چکیده انگلیسی


• Ni (Co) composition-dependent detailed structural analysis of (Ni,Co) DCA powders were examined.
• Depending on the composition ratio, the ferromagnetic ordering can be tuned.
• Variation of superexchange interaction length due to the different size of the transition metal.
• Origin of tunable ordering temperature is related to the different kind of transition metals.

A series of transition metal NixCo1−x(N(CN)2)2 dicyanamide molecular magnet, 0 ≤ x ≤ 1, was chemically synthesized. Structure and magnetic properties were investigated by IR spectroscopy, neutron powder diffraction and temperature-dependent magnetization measurement. The neutron powder diffraction measurement established that all samples showed the rutile structure with Pnnm space group. The detailed Rietveld refinement results revealed a systematic decrease of unit-cell volume with increasing Ni content. We also observed a concurrent increase of the Curie temperature with Ni content due to the increase of superexchange interaction.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Current Applied Physics - Volume 16, Issue 9, September 2016, Pages 1100–1104
نویسندگان
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