کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1786257 1023410 2014 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Photoluminescence study of defect clusters in Cu2ZnSnS4 polycrystals
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Photoluminescence study of defect clusters in Cu2ZnSnS4 polycrystals
چکیده انگلیسی


• New radiative recombination model for Cu2ZnSnS4 is presented.
• The presence of defect clusters in Cu2ZnSnS4 is observed by photoluminescence.
• The PL band at 0.66 eV at T   = 10 K is related to (CuZn−+SnZn2+) defect cluster.
• The PL band at 1.35 eV T   = 10 K is related to (2CuZn−+SnZn2+) defect cluster.

Temperature dependent photoluminescence (PL) study of Cu2ZnSnS4 (CZTS) polycrystals was performed. The low temperature PL spectrum consists of two PL bands: PL1 at 0.66 eV and PL2 at 1.35 eV. We propose a new radiative recombination model involving theoretically predicted (CuZn−+SnZn2+) and (2CuZn−+SnZn2+) defect clusters in nearly stoichiometric CZTS. PL1 band at 0.66 eV is proposed to result from a band-to-impurity type recombination related to a deep donor level at 0.66 eV below CBM that originates from the (CuZn−+SnZn2+) defect cluster. The PL2 band at 1.35 eV is found to be the dominating radiative recombination path that results from the recombination between electrons and holes in the potential wells caused by the (2CuZn−+SnZn2+) clusters that induce a significant band gap decrease of 0.35 eV in CZTS.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Current Applied Physics - Volume 14, Issue 3, March 2014, Pages 447–450
نویسندگان
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