کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1787062 1023430 2012 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrogen permeation of Pd-coated V90Al10 alloy membranes at different pressures in the presence and absence of carbon dioxide
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Hydrogen permeation of Pd-coated V90Al10 alloy membranes at different pressures in the presence and absence of carbon dioxide
چکیده انگلیسی

The hydrogen permeation characteristics of alloy membranes based on Pd-coated V90Al10 alloy membrane have been investigated in the pressure range 1–3 atm under pure hydrogen and hydrogen–carbon dioxide gas mixture at 450 °C. Hydrogen permeation experiments have been confirmed that hydrogen flux was 21.1 ml/min/cm2 for a Pd-coated V90Al10 alloy membrane (thickness: 0.5 mm) using pure hydrogen as the feed gas. It has been found that Pd-coated V90Al10 alloy membranes exhibit good resistance to hydrogen embrittlement in pure hydrogen atmosphere. After different hydrogen permeation flux tests under different pressure condition in presence of hydrogen–carbon dioxide gas mixture, the characteristics of the Pd-coated V90Al10 alloy membranes were examined by ex-situ analysis techniques. The loss of cell performance observed in the presence of hydrogen–carbon dioxide gas mixture is mainly attributed to both physical and chemical degradations of membrane, which led to structural changes in the Pd-coated V90Al10 alloy membrane.


► Hydrogen permeation is inversely proportional to the membrane thickness.
► For a membrane (0.5 mm thickness) the hydrogen flux is 21.1 ml/min/cm2.
► The pressure-flux shows Sievert’s law behavior under hydrogen pressures.
► Carbon dioxide gas influences the hydrogen flux performance.
► Deviation from Sievert’s law is observed in presence of hydrogen–carbon dioxide gas mixture.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Current Applied Physics - Volume 12, Issue 2, March 2012, Pages 394–400
نویسندگان
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