کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
178799 459320 2015 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
An azamacrocyclic electrolyte additive to suppress metal deposition in lithium-ion batteries
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
An azamacrocyclic electrolyte additive to suppress metal deposition in lithium-ion batteries
چکیده انگلیسی


• 1,4,8,11-Tetraazacyclotetradecane (cyclam) is tested as an electrolyte additive.
• Cyclam is electrochemically stable within the working voltage of lithium-ion batteries.
• Deposition of Mn and Fe is greatly suppressed by forming chelate complexes.

An azamacrocyclic compound (1,4,8,11-tetraazacyclotetradecane, cyclam), which forms strong chelate complexes with metal ions such as Mn(II) and Fe(II), is tested as an electrolyte additive to suppress metal deposition. The tetradentate cyclic ligand is electrochemically stable within the working voltage of lithium-ion batteries (0.0–4.5 V vs. Li/Li+), hence it is practicable as an electrolyte additive. Deposition of Mn on a graphite electrode, which is severe when a Li/graphite cell is cycled in a Mn(II)-containing electrolyte solution, is greatly suppressed by adding cyclam. Our elemental analysis reveals negligible Mn deposits on a graphite electrode indicating the beneficial role of cyclam. The suppression of metal deposition is further indicated by the absence of an internal short between Li metal and lithium cobalt oxide positive electrode.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 58, September 2015, Pages 25–28
نویسندگان
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