کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
178930 | 459327 | 2015 | 4 صفحه PDF | دانلود رایگان |
• Ferrocenyl lithioacetylides in THF attach covalently to unconnected electrodes.
• Ethynyl-linked ferrocene and substituted ferrocenes attached to carbon, gold.
• Close to monolayer coverage obtained
• Hundreds or thousands of CV scans possible for modified electrodes
• ‘Spontaneous’ attachment method avoids the need for electrochemical grafting.
Ferrocenes derivatized with a terminal lithioacetylide group react rapidly with unconnected glassy carbon and gold electrodes, giving up to monolayer-level surface coverage. The molecule-to-surface bonding is sufficiently robust to resist sonication, extended storage under dinitrogen, and thousands of repetitive voltammetric scans through the ferrocenyl oxidation wave. This “spontaneous” modification method provides a non-electrochemical pathway to the strong, apparently covalent, attachment of alkynyl-linked molecular tags to carbon and metal surfaces.
Figure optionsDownload as PowerPoint slide
Journal: Electrochemistry Communications - Volume 52, March 2015, Pages 63–66