کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
178946 459328 2015 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Silylation of carbon surfaces through the electrochemical reduction of 2,2′-bipy·R3SiCl adducts
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Silylation of carbon surfaces through the electrochemical reduction of 2,2′-bipy·R3SiCl adducts
چکیده انگلیسی


• 2,2′-Bipyridine forms adducts with monochlorosilanes in solution.
• Anion radicals of bipy-monochlorosilane adducts are formed via one-electron reduction.
• Cleavage of anion radicals of bipy-monochlorosilane results in silyl radicals.
• Efficient addition of triorganosilyl radicals to carbon surface

Electrochemical reduction of complexes of monochlorosilanes with redox-active ligands such as 2,2′-bipy occurs in one-electron fashion at moderately negative potentials, E ≅ − 1 V vs. SCE (in CH3CN/0.1 M Bu4NBF4), leading to silyl radicals. These radicals, trapped with α-phenyl-N-t-butyl-nitrone and characterized as spin-adducts by ESR spectroscopy, add to carbon interfaces (glassy carbon, graphite) providing an efficient method of covalent Si–C silylation of such surfaces. Silylated interfaces were studied by voltammetry, EIS, SEM, EDS, and FTIR spectroscopy.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 53, April 2015, Pages 33–36
نویسندگان
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