کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
179128 459337 2014 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Fluorinated electrolytes for 5-V Li-ion chemistry: Dramatic enhancement of LiNi0.5Mn1.5O4/graphite cell performance by a lithium reservoir
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Fluorinated electrolytes for 5-V Li-ion chemistry: Dramatic enhancement of LiNi0.5Mn1.5O4/graphite cell performance by a lithium reservoir
چکیده انگلیسی


• Li reservoir combined with a fluorinated electrolyte improves high voltage cell performance.
• Conventional electrolyte with Li reservoir also shows improvement but it is short-lived.
• Lithium reservoir can be delivered by Li metal, SLMP or electrochemically prelithiation.

A fluorinated electrolyte was galvanostatically charged and discharged for 100 cycles at an elevated temperature (55 °C) with a LiNi0.5Mn1.5O4 cathode coupled with a graphite anode in the presence of a lithium reservoir. The incorporation of the lithium reservoir was able to compensate for the loss of the active lithium from the LiNi0.5Mn1.5O4 cathode due to the electrolyte oxidative decomposition. Our experimental data demonstrate for the first time that lithium compensation is an efficient way to enhance the performance of high voltage LiNi0.5Mn1.5O4/graphite cell at a high temperature (55 °C).

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 44, July 2014, Pages 34–37
نویسندگان
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