کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
179309 | 459344 | 2013 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
X-ray photoelectron spectroscopy analysis of the effect of alkyl- and arylthio substituents on manganese phthalocyanines for self-assembled monolayer formation on gold
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
• Self assembled monolayers of aryl and alkylthio manganese phthalocyanines are formed.
• X-ray photoelectron spectra are used to characterize the monolayers.
• Arylthio forms better monolayers than alkylthio.
• The monolayers were used to detect thiocyanate with good sensitivity.
Self-assembled monolayers of an octa-substituted alkylthio and arylthio manganese phthalocyanines were formed on gold. X-ray photoelectron spectroscopy was used to analyse both of the phthalocyanine layers on gold. Approximately 60% of the sulphur groups in the aryl substituted-SAM surface were bound to gold through the cleavage of the CS bond, as opposed to only 37% for the alkyl substituted-SAM.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 31, June 2013, Pages 104–107
Journal: Electrochemistry Communications - Volume 31, June 2013, Pages 104–107
نویسندگان
Megan Coates, Tebello Nyokong,