Enhanced spin – Reorientation temperature and origin of magnetocapacitance in HoFeO3

• We report on enhanced spin reorientation transition in HoFe0.5Cr0.5O3 and the magnetocapacitance in the HoFeO3.
• With Cr3+ addition to Fe site, spin reorientation temperature enhanced from 50 K to 150 K and such intriguing phenomena is attributed to the domination of the Ho3+–Fe3+ interaction over the Fe3+–Fe3+ interaction.
• From the decrease in the coercivity with the addition of Cr3+, we believe that there exists magnetic softening for the compound HoFeO3.
• Observed magnetocapacitance in HoFeO3 is correlated to lossy dielectric mechanism of Ho3Fe5O12.

We report on the increase in the spin reorientation temperature in HoFe0.5Cr0.5O3 compound by isovalent substitution (Cr3+) at the Fe-site and the magnetocapacitance in the HoFeO3 compound. Spin reorientation transition is evident around 50 K and 150 K for the x=0 and x=0.5 compounds respectively. The increase in the spin reorientation transition temperature in case of x=0.5 compound can be attributed to the domination of the Ho3+–Fe3+ interaction over the Fe3+–Fe3+ interaction. Decrease in Néel temperature from 643 K (x=0) to 273 K (x=0.5) can be ascribed to the decrease in the interaction between antiferromagnetically aligned Fe3+ moments as a result of the dilution of the Fe3+ moments with the Cr3+ addition. From the magnetization M vs. magnetic field H variation it is evident that the coercivity, HC decreases for x=0.5 compound, hinting the magnetic softening of the HoFeO3 compound. Observed magnetocapacitance could be due to lossy dielectric mechanism in the present compound. Indeed, present results would be helpful in understanding the physics behind rare-earth orthoferrites.