کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1800432 1024528 2011 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of preparation conditions on fractal structure and phase transformations in the synthesis of nanoscale M-type barium hexaferrite
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Effect of preparation conditions on fractal structure and phase transformations in the synthesis of nanoscale M-type barium hexaferrite
چکیده انگلیسی

The conditions of the synthesis of carbonate-hydroxide precursors (pH of FeOOH precipitation and heat treatment regimes) were studied in terms of their effect on the fractal structure and physical–chemical properties of precursors. Phase transformations which occur during the synthesis of nanosize M-type barium hexaferrite (BHF) were studied as well.The first structural level of precursors' aggregation for mass fractals, the correlation between fractal dimension and precursors' activity during the synthesis of BHF were determined.Synthesis parameters for the precursors with the optimal fractal structure were determined. These data permit an enhancement of the filtration coefficient of the precipitates by a factor of 4–5, obtaining substantial decrease in the temperature required for synthesis of a single-phase BHF, and monodispersed plate-like nanoparticles (60 nm diameter) with the shape anisotropy and good magnetic characteristics (saturation magnetization (Ms)=68,7 emu/g and coercitivity (Hc)=5440 Oe).


► The nanosize M-type BHF obtained by precipitation of hydroxicarbonates technique.
► Optimal fractal structure of a precursor for nanosize M-type BHF has been determined.
► The precursor precipitated at pH 4.3 allows getting monodisperse particles of BHF.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetism and Magnetic Materials - Volume 323, Issue 20, October 2011, Pages 2497–2503
نویسندگان
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