کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
180320 | 459377 | 2011 | 4 صفحه PDF | دانلود رایگان |
A straight-forward method for the synthesis of metal-free catalysts for oxygen reduction by thermal treatment of a mixture of poly(3,5-pyridine) with carbon black in helium is reported. The catalyst was characterized by X-ray diffraction and photoelectron spectroscopy, cyclic voltammetry and rotating disk electrode measurements. The new catalyst exhibited remarkable activity similar to Pt-based catalysts in alkaline media.
Research highlights
► A method for synthesis of a metal-free catalyst for oxygen reduction was developed.
► The method involves pyrolysis of a mixture of polypyridine with Vulcan carbon.
► A polymer to carbon ratio of 2:5, pyrolyzed at 800 °C yielded the most active catalyst.
► The catalyst exhibits remarkable activity comparable to platinum based catalysts.
Journal: Electrochemistry Communications - Volume 13, Issue 6, June 2011, Pages 593–596