کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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180732 | 459387 | 2010 | 4 صفحه PDF | دانلود رایگان |
This study aimed at fabricating porous crack-free and delamination-free La0.6Sr0.4CoO3−δ electrodes using nanopowders and investigating oxygen reduction (occurring at solid oxide fuel cell cathodes) and oxygen evolution (occurring at solid oxide electrolysis cell anodes) at 600 °C in air. The electrodes were deposited by screen-printing on Ce0.8Gd0.2O1.9 substrates. The pastes were prepared with nanoparticles synthesised by flame spray synthesis and graphite pore former. Without graphite, the electrodes sintered at 1000 °C exhibit relatively low porosity and significant densification which led to partial delamination and large overpotentials. The addition of graphite, which was removed by combustion at ca. 650 °C during sintering, markedly improves electrode performance by increasing porosity and reducing densification. A minimal overpotential for both the oxygen reduction and oxygen evolution was reached for a layer porosity of ca. 50–60 vol.%.
Journal: Electrochemistry Communications - Volume 12, Issue 2, February 2010, Pages 292–295