کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
180910 | 459391 | 2009 | 4 صفحه PDF | دانلود رایگان |
A polymeric activated carbon (PAC) was synthesized from the carbonization of a resorcinol–formaldehyde resin with KOH served as an activation agent. The nitrogen adsorption–desorption at 77 K, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were used to characterize the prepared PAC. Compared with the commercial activated carbon (Maxsorb: Kansai, Japan), PAC shows superior capacitive performance in terms of specific capacitance, power output and high energy density as electrode materials for supercapacitors. PAC presents a high specific capacitance of 500 F g−1 in 6 mol l−1 KOH electrolyte at a current density of 233 mA g−1 which remained 302 F g−1 even at a high current density of 4.6 A g−1. The good electrochemical performance of the PAC was ascribed to well-developed micropores smaller than 1.5 nm, the presence of electrochemically oxygen functional groups and low equivalent series resistance.
Journal: Electrochemistry Communications - Volume 11, Issue 3, March 2009, Pages 715–718