کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
180985 459393 2010 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Polyimide gel polymer electrolyte-nanoencapsulated LiCoO2 cathode materials for high-voltage Li-ion batteries
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Polyimide gel polymer electrolyte-nanoencapsulated LiCoO2 cathode materials for high-voltage Li-ion batteries
چکیده انگلیسی

We demonstrate a novel and facile approach to surface modification of high-voltage charged LiCoO2, which is based on encapsulating LiCoO2 by a polyimide (PI) gel polymer electrolyte layer. The PI is introduced onto the LiCoO2 by thermally curing 4-component (pyromellitic dianhydride/biphenyl dianhydride/phenylenediamine/oxydianiline) polyamic acid. The PI nanoencapsulating layer features the high surface coverage, nanometer thickness, and facile ion transport. These unique characteristics are expected to enable the PI coating layer to effectively suppress the undesirable interfacial reaction of the LiCoO2 with liquid electrolyte, which plays a key role in noticeably improving the 4.4 V cycle performance and mitigating the vigorous exothermic reaction between the charged LiCoO2 and liquid electrolyte.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 12, Issue 8, August 2010, Pages 1099–1102
نویسندگان
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