کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
181402 459402 2008 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Stripping voltammetric analysis of organophosphate pesticides based on solid-phase extraction at zirconia nanoparticles modified electrode
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Stripping voltammetric analysis of organophosphate pesticides based on solid-phase extraction at zirconia nanoparticles modified electrode
چکیده انگلیسی

A sensitive electrochemical stripping voltammetric method for analyzing organophosphate (OP) compounds was developed based on solid-phase extraction (SPE) at zirconia (ZrO2) nanoparticles modified electrode. ZrO2 nanoparticles were proved as a new sorbent for SPE of OP pesticides. Because of the strong affinity of ZrO2 for the phosphoric group, nitroaromatic OPs can strongly bind to the ZrO2 nanoparticle surface. The combination of SPE with square-wave voltammetry (SWV) provided a fast, sensitive, and selective electrochemical method for nitroaromatic OP compounds using methyl parathion (MP) as a model. The stripping response was highly linear over the MP range of 0.003–2.0 μg/mL, with a detection limit of 0.001 μg/mL. The fast extraction ability of ZrO2 nanoparticles makes it promising sorbent for various solid-phase extractions.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 10, Issue 5, May 2008, Pages 686–690
نویسندگان
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