کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
181574 | 459405 | 2009 | 4 صفحه PDF | دانلود رایگان |
A novel all-solid-state thin-film-type rechargeable lithium-ion battery employing in situ prepared both positive and negative electrode materials is proposed. A lithium-ion conducting solid electrolyte sheet of Li2O–Al2O3–TiO2–P2O5-based glass–ceramic manufactured by OHARA Inc. (OHARA sheet) was used as the solid electrolyte, which was sandwiched by Cu and Mn metal films. The Cu/OHARA sheet/Mn layer became an all-solid-state lithium-ion battery after applying d.c. 16 V to the layer, and the resultant battery operated at 0.3–0.8 V with reversible capacity of 0.45 μAh cm−2. High voltage battery was successfully prepared by applying the d.c. high voltage to a five-series of Cu/OHARA sheet/Mn layer, resulting in all-solid-state battery operating at 1.5–4.0 V. The proposed fabrication process will become a new technology to develop advanced all-solid-state rechargeable lithium-ion batteries.
Journal: Electrochemistry Communications - Volume 11, Issue 2, February 2009, Pages 413–416