کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
182007 | 459414 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The mechanism of formic acid electrooxidation on iron tetrasulfophthalocyanine-modified platinum electrode
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The mechanism of formic acid electrooxidation on iron tetrasulfophthalocyanine-modified platinum electrode The mechanism of formic acid electrooxidation on iron tetrasulfophthalocyanine-modified platinum electrode](/preview/png/182007.png)
چکیده انگلیسی
The mechanism of formic acid electrooxidation on iron tetrasulfophthalocyanine (FeTSPc) modified Pt electrode was investigated with electrochemical methods. It was found that a “third-body” effect of FeTSPc on Pt electrode predominates during the electrooxidation process based on unusual electrochemical results. The modification leads formic acid electrooxidation to take place through a desired direct pathway, in which the mechanism is proposed to be the gradual dehydrogenation of formic acid and the reaction of formate with hydroxyl species.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 10, Issue 1, January 2008, Pages 131–135
Journal: Electrochemistry Communications - Volume 10, Issue 1, January 2008, Pages 131–135
نویسندگان
Zhonghua Zhang, Xiaochun Zhou, Changpeng Liu, Wei Xing,