کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
182549 | 459431 | 2007 | 8 صفحه PDF | دانلود رایگان |
Pt particles of 20% Pt/C samples grew both by repetitive potential cycling and heat treatment. Average particle size variation is linearly proportional to the number of potential cycles while it is proportional to an exponential function of heating temperature. HR-TEM results show rough and irregular Pt surfaces in repetitively potential cycled samples and well-defined cubo-octahedrons without many defects in heat treated samples. This difference of surface morphology plays a main role to produce opposite electrocatalytic activity variation versus particle size of the samples prepared by potential cycling and heat treatment. Our results demonstrate that in terms of noble metal usage Pt particles with an average size of ∼5 nm is the most efficient catalyst if the particle shapes are well defined cubo-octahedrons. In that aspect, heat treatment is better than potential cycling to prepare catalysts.
Journal: Electrochemistry Communications - Volume 9, Issue 2, February 2007, Pages 317–324