کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
2028857 1070447 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Unusual electrochemical oxidation of cholesterol
موضوعات مرتبط
علوم زیستی و بیوفناوری بیوشیمی، ژنتیک و زیست شناسی مولکولی زیست شیمی
پیش نمایش صفحه اول مقاله
Unusual electrochemical oxidation of cholesterol
چکیده انگلیسی

It has been found that cholesterol undergoes direct electrochemical oxidation on platinum electrode in dichloromethane. Voltammetric measurements show that the process is controlled by the rate of electron transfer and the height of the oxidation peak is linear vs. concentration of cholesterol. Preparative electrolysis with separated cathodic and anodic compartments afforded dicholesteryl ether in a relatively high material yield. Depending on electrolysis conditions (composition of supporting electrolyte and electrolytic cell construction) various by-products with a 3β-chloro, 3β-acetoxy, or 3β-acetylamino group were obtained.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Steroids - Volume 73, Issue 5, May 2008, Pages 543–548
نویسندگان
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