کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
226742 | 464802 | 2015 | 16 صفحه PDF | دانلود رایگان |
• Methyl acrylate connects covalently with alkylpyridinium bromide to produce MPA-n.
• MPA-n adsorbs on X70 steel surface via O atom of MA moiety and positive pyridinium ring.
• The interaction energy of MPA-n with iron increases with prolonging the alkyl chain.
Methyl acrylate connects covalently with alkylpyridinium bromide to build N-alkyl-3-(2-methoxycarbonyl-vinyl)pyridinium bromide (MPA-n, n = 8–14). MPA-n inhibited X70 steel from corrosion in 5 M HCl with inhibition efficiency of 98% and the inhibition capacity was in the order of MPA-14 > MPA-12 > MPA-10 > MPA-8. Quantum chemical calculation unveiled that MPA-n adsorbed on iron surface by O atom in MA moiety offering electrons to d orbital of iron and by π* orbital of pyridinium accepting electrons from iron, and MPA-n with longer alkylchain possessed higher EHOMO, lower ΔE, larger molecular volume and dipole moment, all suggesting the same corrosion inhibition order as that in experiments.
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Journal: Journal of Industrial and Engineering Chemistry - Volume 27, 25 July 2015, Pages 133–148