کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
229061 | 464857 | 2013 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Selective oxidation of HMF to DFF using Ru/γ-alumina catalyst in moderate boiling solvents toward industrial production
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Selective oxidation of 5-hydroxymethyl-2-furfural (HMF) to 2,5-diformylfuran (DFF) toward industrial production was studied over Ru supported γ-alumina catalyst using molecular oxygen as an oxidant. From the solvents screening, considering recyclability after reaction, toluene was found to be the best solvent and gave maximum conversion of 99% with 97% DFF selectivity at 130 °C and 40 psi O2 pressure. Catalyst was washed with NaOH solution of pH = 12 to remove the adsorbed polymer impurities and then reused up to 5 cycles. The product could be purified by simple evaporation of the solvent, which could add advantage for industrial process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Industrial and Engineering Chemistry - Volume 19, Issue 3, 25 May 2013, Pages 1056–1059
Journal: Journal of Industrial and Engineering Chemistry - Volume 19, Issue 3, 25 May 2013, Pages 1056–1059
نویسندگان
Churchil A. Antonyraj, Jaewon Jeong, Bora Kim, Seunghan Shin, Sangyong Kim, Kwan-Young Lee, Jin Ku Cho,