کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
229701 465041 2015 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
N-heterocyclic carbene catalyzed synthesis of dimethyl carbonate via transesterification of ethylene carbonate with methanol
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
N-heterocyclic carbene catalyzed synthesis of dimethyl carbonate via transesterification of ethylene carbonate with methanol
چکیده انگلیسی

An organocatalytic protocol for the synthesis of dimethyl carbonate has been developed. Under the catalysis of 5 mol% N-heterocyclic carbenes, ethylene carbonate undergoes transesterification reaction with methanol under very mild reaction conditions, producing dimethyl carbonate with high efficiency. Furthermore, this N-heterocyclic carbene promoted transesterification can be scaled-up easily without lose of the conversion of dimethyl carbonate.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Saudi Chemical Society - Volume 19, Issue 1, January 2015, Pages 112–115
نویسندگان
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