کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
230864 1427401 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydration of terminal alkynes on Nafion film in supercritical carbon dioxide
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Hydration of terminal alkynes on Nafion film in supercritical carbon dioxide
چکیده انگلیسی

To find out the conditions for mild hydration of carbon–carbon triple bonds the hydration reactions of some terminal alkynes (FcCCH, PhCCH, C5H11CCH) on the Nafion film in supercritical carbon dioxide (sc-CO2) were studied. The corresponding ketones were prepared in excellent yields. The hydration of 1-heptyne is accompanied by the isomerization of the terminal carbon–carbon triple bond into the internal one under acidic heterogeneous catalysis.

Figure optionsDownload as PowerPoint slideHighlights
► Nafion film hydrates terminal alkynes RCCH (RFc, Ph, C5H11) in sc-CO2 under mild conditions to give the respective ketones in excellent yields.
► The ecological compatibility and easy isolation of the reaction products are obvious advantages of this catalytic system.
► The terminal carbon–carbon triple bond in hept-1-yne was shown to migrate into the internal position under the acid heterogeneous catalysis conditions.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Supercritical Fluids - Volume 76, April 2013, Pages 61–66
نویسندگان
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