کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
230864 | 1427401 | 2013 | 6 صفحه PDF | دانلود رایگان |

To find out the conditions for mild hydration of carbon–carbon triple bonds the hydration reactions of some terminal alkynes (FcCCH, PhCCH, C5H11CCH) on the Nafion film in supercritical carbon dioxide (sc-CO2) were studied. The corresponding ketones were prepared in excellent yields. The hydration of 1-heptyne is accompanied by the isomerization of the terminal carbon–carbon triple bond into the internal one under acidic heterogeneous catalysis.
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► Nafion film hydrates terminal alkynes RCCH (RFc, Ph, C5H11) in sc-CO2 under mild conditions to give the respective ketones in excellent yields.
► The ecological compatibility and easy isolation of the reaction products are obvious advantages of this catalytic system.
► The terminal carbon–carbon triple bond in hept-1-yne was shown to migrate into the internal position under the acid heterogeneous catalysis conditions.
Journal: The Journal of Supercritical Fluids - Volume 76, April 2013, Pages 61–66