کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
232330 | 1427482 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Low temperature hydrogenation of 1- and 2-phenylethanols with noble metal catalysts in supercritical carbon dioxide
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Catalytic ring hydrogenation of 1- and 2-phenylethanols was studied over several noble metal catalysts supported on charcoal or γ-alumina in supercritical carbon dioxide. The major products formed were corresponding cyclohexylethanols via aromatic ring hydrogenation of 1- and 2-phenylethanols while by products, ethylbenzene and cyclohexylethane were formed in minor quantities due to dehydroxylation reaction. A charcoal supported ruthenium catalyst gave the highest selectivity to (>80%) cyclohexylethanols among the other catalysts tested in this study at 323 K in supercritical carbon dioxide solvent.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Supercritical Fluids - Volume 37, Issue 1, February 2006, Pages 87–93
Journal: The Journal of Supercritical Fluids - Volume 37, Issue 1, February 2006, Pages 87–93
نویسندگان
Takafumi Sato, Osamu Sato, Kunio Arai, Eiichi Mine, Norihito Hiyoshi, Chandrashekhar V. Rode, Masayuki Shirai,