کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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237164 | 465697 | 2012 | 8 صفحه PDF | دانلود رایگان |

The optimal conditions for preparation of activated carbons from date stones by ferric chloride activation (FAC) and commonly used zinc chloride activation (ZAC) were investigated. The influence of activation time, activation temperature, and impregnation ratio on the yield and phenol (Ph) uptake of such carbons were studied. Based on Box–Wilson central composite design, two second order polynomial models were developed to correlate the process variables to the two responses. From the analysis of variance the significant variables on each response were identified. For FAC, an optimum condition of 76 min activation time, 707 °C activation temperature, and 1.6 impregnation ratio gave 97.96 mg/g Ph uptake and 47.24% yield, while for ZAC, 86.11 mg/g Ph uptake and 39.16% yield were obtained at 30 min activation time, 717 °C activation temperature, and 0.5 impregnation ratio. The Langmuir isotherm was used to correlate equilibrium data of Ph adsorption, showing maximum Ph uptake of 170.97 and 161.54 mg/g for FAC and ZAC, respectively. Also, the characteristics of both carbons were determined and found to have surface areas of 780.06 and 1045.61 m2/g, respectively.
The optimal conditions for preparation of date stones-based activated carbons by activation with ferric chloride (FAC) and commonly used zinc chloride (ZAC) were investigated. The surface areas of such carbons were 780.06 and 1045.61 m2/g, respectively. The yields of FAC and ZAC were 47.24 and 39.16 %, respectively. Maximum phenol uptake of 170.97 and 161.54 mg/g were reported for FAC and ZAC, respectively.Figure optionsDownload as PowerPoint slideHighlights
► Activated carbons were prepared from date stones by FeCl3 and ZnCl2 activation.
► The characteristics of such carbons were determined.
► The optimum preparation conditions were determined using RSM.
► Phenol has been successively removed from aqueous solution.
► Phenol adsorption data were well fitted to the Langmuir isotherm.
Journal: Powder Technology - Volume 224, July 2012, Pages 101–108