Electrochemical Behavior of Metal Complexes with a N2S2 Ligand

In this work we present a solid state characterization and the electrochemical behavior of metal complexes with Cu(II) and Co(II) and the ligand 1,8-bis(2-pyridyl)-3,6-dithiaoctane pdto;[Cu(pdto)H2O](NO3)2, [Cu(pdto)H2O](PF6)2, and [Co(pdto)Cl2] in non-aqueous solvents, in order to understand how the flexibility and the electronic properties of pdto affect the electrochemical response of each coordination compound.