The Study of Redox Electrode Processes of Sulfur-Containing Compounds by Voltammetry

In this work the general case of quasi-reversible redox electrode processes of thiol compounds proceeding on a mercury-film electrode via a CE (chemical-electrochemical) mechanism has been revealed and investigated by voltammetry. The quantitative criteria for correlation between theory and experiment corresponding to a CE mechanism and new approach for estimating the kinetic parameters of the preceding chemical reaction have been suggested.