Release of antioxidants from co-extruded active packaging developed for whole milk powder

Control of oxidation is a basic criterion to maintain the quality of milk and dairy products. Multilayer co-extruded films are often used to limit the diffusion of oxygen from the environment into the package. In this study, multilayer co-extruded films made of high density polyethylene (added with titanium dioxide), ethylene vinyl alcohol and a layer of low density polyethylene containing the antioxidants butylated hydroxyanisole (1.5%), butylated hydroxytoluene (1.5%) and α-tocopherol (4%) were manufactured. The release of the antioxidants from the films to whole milk powder was determined during 30 days at 30 °C. Whole milk powder stability was measured by monitoring vitamin A, hexanal, pentanal and heptanal content. Butylated hydroxytoluene and butylated hydroxyanisole migrated quickly from the films to the milk powder, while α-tocopherol migrated gradually. Multilayer co-extruded films provided an adequate light-barrier for whole milk powder and the film added with α-tocopherol contributed to the protection of vitamin A degradation compared with the other films.