کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
244172 501944 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Tetramethylguanidine as an efficient catalyst for transesterification of waste frying oils
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی مهندسی انرژی و فناوری های برق
پیش نمایش صفحه اول مقاله
Tetramethylguanidine as an efficient catalyst for transesterification of waste frying oils
چکیده انگلیسی

New catalysts and environmentally benign processes may lead to methyl ester production with improved properties at competitive costs. In this study, transesterification of waste frying oil to biodiesel using tetramethylguanidine as a strong base catalyst was conducted. The influence of catalyst concentration and of certain physicochemical properties of waste frying oil was investigated. Experiments were also performed on a semi-refined cottonseed oil for comparison purposes. Experimental results showed that methyl ester conversion was dependent on the type of oil, catalyst concentration and reaction time.


► Tetramethylguanidine provides a clean and water-free process for biodiesel production.
► The conversion of cottonseed oil is more than 96.5% at 2 wt.% of TMG.
► Lower conversion was found for waste oil due to the presence of free fatty acids.
► No formation of soaps occurred due to the formation of amides and amine salts.
► Extensive distillation is required to remove and recycle the excess catalyst.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Energy - Volume 88, Issue 11, November 2011, Pages 3645–3650
نویسندگان
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