کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
40494 | 45856 | 2013 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Performance and deactivation of Ir-based catalyst during hydroxylammonium nitrate catalytic decomposition Performance and deactivation of Ir-based catalyst during hydroxylammonium nitrate catalytic decomposition](/preview/png/40494.png)
The catalytic performance of Ir-based catalyst for the decomposition of high energetic liquid propellant was investigated in a monopropellant thruster. The changes of ignition delay, catalyst bed temperature and chamber pressure with the numbers of pulse-injection were demonstrated to be effective signposts of catalyst bed efficiencies. The catalyst in fresh state and that after its deactivation were characterized by N2-physisorption, XRD, H2-chemisorption, TEM, H2-TPR and XPS. It was noted that the particle distribution and oxidation state of iridium are the major indicators of catalyst deactivation.
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► Uniform distribution of nano-size iridium particles into the alumina before test.
► Deactivation of iridium catalyst after HAN decomposition.
► Deactivation phenomena was caused by oxidation of iridium.
► Severe sintering of iridium catalyst after HAN decomposition reaction.
Journal: Applied Catalysis A: General - Volume 452, 15 February 2013, Pages 64–68