Remediation of actual groundwater polluted with nitrate by the catalytic reduction over copper–palladium supported on active carbon

Catalytic reduction of nitrate (NO3−) in groundwater over a Cu–Pd catalyst supported on active carbon was investigated in a gas–liquid co-current flow system at 298 K. Although Cu–Pd/active carbon, in which the Cu/Pd molar ratio was more than 0.66, showed high activity, high selectivity for the formation of N2 and N2O (98%), and high durability for the reduction of 100 ppm NO3− in distilled water, the catalytic performance decreased during the reduction of NO3− in groundwater. The catalyst also irreversibly deactivated during the reaction in groundwater. The organic species in the groundwater caused the decrease in the catalytic performance and the irreversible catalyst deactivation. Ozone-treatment of the groundwater to remove the organic species substantially helped to maintain the catalytic activity and to halt the irreversible deactivation of the catalyst. Chloride ion (Cl−) in the groundwater also caused the decrease in the activity and selectivity, but the effects of Cl− were reversible. Sulfate ion (SO42−) and cations, including Mg2+, Ca2+ and K+, had little or no effect on the catalytic performance of Cu–Pd/active carbon, though they were present in the groundwater sample. More than an allowable level of NH3 (NH4+) was formed during the catalytic reduction of NO3− in the groundwater, but was completely removed by the cation-exchange process using Na-mordenite.

Ozone-treatment of actual groundwater polluted with NO3− substantially helped to maintain the catalytic activity of Cu–Pd/active carbon due to removal of organic compounds in the groundwater. While Cl− in the groundwater caused the decrease in the activity and selectivity, a process of ozone pre-treatment, catalytic reduction using Cu–Pd/active carbon, and ion-exchange with Na-mordenite remediated the actual groundwater.Figure optionsDownload as PowerPoint slide