کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
42646 45935 2009 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Selectivity enhancement in the catalytic hydrogenation of propionitrile using ionic liquid multiphase reaction systems
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Selectivity enhancement in the catalytic hydrogenation of propionitrile using ionic liquid multiphase reaction systems
چکیده انگلیسی

A new ionic liquid based, multiphase reaction system was investigated for the catalytic hydrogenation of propionitrile. The reaction system under investigation consisted of a solid heterogeneous Ru-catalyst (Ru on carbon), two liquid phases and the hydrogen gas-phase. By using two liquid phases in the reactor – of which one was an ionic liquid – it was possible to improve significantly the selectivity for the formation of propylamine by suppressing consecutive reactions to dipropylamine and tripropylamine. This enhanced selectivity resulted either from the protonation of the primary formed amine (in case of the Brønsted acidic ionic liquids dimethylcyclohexylammonium hydrogensulfate and 1-butylimidazolium hydrogensulfate) or from the extraction of the primary amine into the organic phase (in case of a 1-ethyl-3-methylimidazolium ethylsulfate/1,2,4-trichlorobenzene biphasic system).

An approach to improve the primary amine selectivity in nitrile hydrogenation is presented. The new concept was carried out in a multiphase system comprising two liquid phases, namely an ionic liquid and an organic solvent. The new concepts led to an increase in propylamine selectivity from approx. 50% in the IL-free reference system up to 85% in the IL system.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 356, Issue 1, 1 March 2009, Pages 43–51
نویسندگان
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