کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
42919 45947 2009 6 صفحه PDF سفارش دهید دانلود رایگان
عنوان انگلیسی مقاله ISI
Dynamic modeling and simulation of heavy paraffin dehydrogenation reactor for selective olefin production in linear alkyl benzene production plant
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موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Dynamic modeling and simulation of heavy paraffin dehydrogenation reactor for selective olefin production in linear alkyl benzene production plant
چکیده انگلیسی

Modeling of a heterogeneous industrial fixed bed reactor for selective dehydrogenation of heavy paraffin with Pt–Sn–Al2O3 catalyst has been the subject of current study. Using mass balance, momentum balance for appropriate element of reactor and applying pressure drop, rate and deactivation equations, a detailed model of the reactor has been obtained. Mass balance equations have been used for five different components. In order to investigate reactor performance in time, the reactor model which is a set of partial differential equations (PDEs), ordinary differential equations and algebraic equations has been solved numerically.Variation of paraffins, olefins, dienes, aromatics and hydrogen mole percent as a function of time and reactor radius have been found by numerical solution of the model. Modeling results have been compared with an industrial reactor data at different operating times. The comparison successfully confirms validity of the proposed model.It was found that at radius of 0.75–0.68 m of catalytic bed, there is not sensible conversion of paraffin as surface reaction is rate determining. At entrance of the bed variation of diene was near zero. Hydrogen production was high at entrance of the catalytic bed. Hydrogen production decreases along the reactor bed because of olefin cracking.

Modeling of a heterogeneous industrial fixed bed reactor for selective dehydrogenation of heavy paraffin with Pt–Sn–Al2O3 catalyst has been the subject of current study. A detailed model of the reactor has been developed. In order to estimate reactor production by the passage of time, the reactor model which is a set of partial differential equations (PDEs), ordinary differential equations and algebraic equations has been solved numerically.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 358, Issue 1, 30 April 2009, Pages 1–6
نویسندگان
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