کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
43567 | 45977 | 2008 | 7 صفحه PDF | دانلود رایگان |
Four dinuclear alkylidene-bridged zirconocene complexes were synthesized applying hydrozirconation reaction of α,ω-dienes with the “Schwartz’ reagent” and tested for the polymerization of ethylene. The polyethylenes obtained with alkylidene-bridged dinuclear complexes showed higher molecular weights Mw and polydispersities revealing that more catalytically active species exist in the polymerization system.
Four dinuclear alkylidene-bridged zirconocene complexes were synthesized applying hydrozirconation reaction of α,ω-dienes with the “Schwartz’ reagent” and tested for the polymerization of ethylene. The polyethylenes obtained with alkylidene-bridged dinuclear complexes showed higher molecular weights Mw and polydispersities revealing that more than one catalytically active species exist in the polymerization system. Figure optionsDownload as PowerPoint slide
Journal: Applied Catalysis A: General - Volume 348, Issue 1, 30 September 2008, Pages 79–85