کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
43743 45986 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Kinetic characterization of a bioinspired, heterogeneously active macromolecular catalyst for phenol oxidation and coupling reactions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Kinetic characterization of a bioinspired, heterogeneously active macromolecular catalyst for phenol oxidation and coupling reactions
چکیده انگلیسی

We have synthesized and characterized a novel copper metalated polymeric matrix of modified nucleobase cytosine that catalyses oxidation of phenolic substrates. This metalated polymer is insoluble in common organic solvents, thus catalysis is heterogeneous in nature so that the material can be reused. The molecular structure of the monomer and the metalated monomer, a Michaelis–Menten kinetic analysis of oxidative transformations using different phenolic substrates and mechanistic investigations are presented in this paper.

This report describes a novel cytosine containing copper metalated polymeric matrix possessing phenol oxidative and coupling activities. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 316, Issue 1, 2 January 2007, Pages 100–106
نویسندگان
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