کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
43771 | 45987 | 2008 | 6 صفحه PDF | دانلود رایگان |
A smart and greener microwave approach to the selective oxidation of cyclohexene is reported whereby, depending on the reaction conditions, the epoxide (65% conversion, 75% selectivity), the enol (70% conversion, 80% selectivity) or the enone (>99% conversion, 89% selectivity) can be obtained in a short period of time ranging from 1 to 20 min. A cobalt-salen-SBA-15 material was employed as catalyst. The reported solventless microwave protocol was simple, greener and more efficient compared to any other reported cyclohexene oxidations.
A smart and greener approach to the selective oxidation of cyclohexene is reported whereby, depending on the reaction conditions, the epoxide, the enol or the enone can selectively be obtained. A cobalt-salen-SBA-15 material was employed as catalyst. The reported protocol was simple, greener and more efficient compared to any reported cyclohexene oxidations.Figure optionsDownload as PowerPoint slide
Journal: Applied Catalysis A: General - Volume 341, Issues 1–2, 15 June 2008, Pages 154–159