کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
43961 | 45997 | 2006 | 10 صفحه PDF | دانلود رایگان |
The present study confirmed that crystalline nanofibers with controlled structure may be prepared at different reaction temperatures over Ni deposited on Fe pillared clays. It was found a large catalytic effect over the growth of carbon nanofibers at temperatures between 450 and 650 °C. TEM pictures revealed different types of CNFs as a function of the reaction temperature: platelet type structures at 450 °C, both platelet and fishbone type structures at 550 °C, and tubular type structures that started to be produced at temperatures above 600 °C. CNFs associated with a reaction temperature of 650 °C were characterized by a very broad diameter distribution; some CNFs had diameters much higher than the freshly reduced metal crystallites. The arrangement of graphite sheets shifted from a situation where a large fraction of the edge sites would be available for gas adsorption to other in which a minor fraction of these sites were available. As a consequence, the CNFs surface area tended to decrease in increasing the reaction temperature. Finally, some improvement of stacking and removal of defects were achieved by raising the reaction temperature.
Journal: Applied Catalysis A: General - Volume 301, Issue 1, 10 February 2006, Pages 123–132