کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
44332 46015 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Catalytic isosafrol oxidation mediated by impregnated and encapsulated vanadyl-Y-zeolite under microwave irradiation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Catalytic isosafrol oxidation mediated by impregnated and encapsulated vanadyl-Y-zeolite under microwave irradiation
چکیده انگلیسی

Piperonal is an important intermediate in the synthesis of drugs like l-DOPA. Vanadyl-Y-zeolites have been tested as potential catalysts for this process. The use of encapsulated vanadyl compounds in Y-zeolite pores led to excellent rates of isosafrol oxidation under microwave irradiation. Native Y-zeolite better allowed the diffusion of the oxidant agent (hydrogen peroxide) through the catalyst pores compared to the VO-exchanged catalysts. This led to piperonal, which was also obtained due to the presence of V5+ supported on one of the catalysts. These factors aided the extension of the oxidation process of isosafrol. On the other hand, vanadyl-zeolites, containing V4+ species, promoted the reaction to intermediate (epoxide) with high selectivity under microwave radiation. Finally the impregnation of VO(Salen) on Y-zeolite showed better selectivity for epoxide formation than did the incorporated VO(Salen)-zeolite. Catalyst's surface area and availability of the vanadyl group were the main factors which allowed this superior performance.

The paper reports the characterization of vanadyl-Y-zeolites produced via impregnation and encapsulation methods. Their catalytic activities for isosafrol oxidation, promoted via microwave irradiation, were evaluated in contrast of well-known catalysts, as V2O5/Y-zeolite composites and non-exchanged zeolite. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 326, Issue 1, 30 June 2007, Pages 82–88
نویسندگان
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