کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
44404 | 46024 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Acylation of 2-methoxynaphthalene with acetic anhydride over silica-embedded triflate catalysts
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Acylation of 2-methoxynaphthalene with acetic anhydride over silica-embedded triflate catalysts Acylation of 2-methoxynaphthalene with acetic anhydride over silica-embedded triflate catalysts](/preview/png/44404.png)
چکیده انگلیسی
Silica sol–gel immobilized triflate compounds like La(OTf)3, tert-butyldimethylsilyl trifluoromethanesulfonate (BDMST) and triflic acid (HOTf) were tested in the acylation of 2-methoxynaphthalene with acetic anhydride, leading to 1-acetyl-2-methoxynaphthalene as the major product. The reaction only proceeded with good yields on BDMST and HOTf catalysts, while La(OTf)3 presented a low activity. For BDMST in solvent-free conditions, the resulting TOF was superior to that reported in literature for other heterogeneous catalysts and even for homogeneous triflates. The rates of reactions in various solvents strongly depend on the donor number of these solvents.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 306, 7 June 2006, Pages 159–164
Journal: Applied Catalysis A: General - Volume 306, 7 June 2006, Pages 159–164
نویسندگان
A.N. Pârvulescu, B.C. Gagea, V.I. Pârvulescu, D. De Vos, P.A. Jacobs,