کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
44449 | 46030 | 2007 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Ce-silica mesoporous SBA-15-type materials for oxidative catalysis: Synthesis, characterization, and catalytic application Ce-silica mesoporous SBA-15-type materials for oxidative catalysis: Synthesis, characterization, and catalytic application](/preview/png/44449.png)
Cerium-containing mesoporous materials have been synthesized by hydrothermal method and characterized by IR, DR-UV–vis and DRIFT spectroscopy, XRD and N2 adsorption methods. It was established that the d100 and unit-cell (a0) parameter increase with the increase of cerium content up to 2% in SBA-15 and then tend to remain the same. According to DR-UV–vis spectroscopic data, an agglomeration of cerium atoms was observed in the form of fine CeO2 crystallites. Important factors affecting the catalytic activity of Ce-SBA-15, namely the effect of cerium content, the state of cerium ions, the state of silanol groups on the surface of Ce-SBA-15, and stability of the catalyst have been studied in the cyclohexanol and cyclohexene oxidation with hydrogen peroxide.
Cerium-containing mesoporous materials have been synthesized by hydrothermal method and characterized by IR, DR-UV–vis and DRIFT spectroscopy, XRD and N2 adsorption methods. Important factors affecting the catalytic activity of Ce-SBA-15, namely the effect of cerium content, the state of cerium ions, the state of silanol groups on the surface of Ce-SBA-15 and stability of the catalyst have been studied in the cyclohexanol and cyclohexene oxidation with hydrogen peroxide. The reaction mechanism was discussed.Figure optionsDownload as PowerPoint slide
Journal: Applied Catalysis A: General - Volume 317, Issue 1, 27 January 2007, Pages 1–10