کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
44549 | 46041 | 2006 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Rhenium oxide supported on organized mesoporous alumina — A highly active and versatile catalyst for alkene, diene, and cycloalkene metathesis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Rhenium oxide supported on organized mesoporous alumina — A highly active and versatile catalyst for alkene, diene, and cycloalkene metathesis Rhenium oxide supported on organized mesoporous alumina — A highly active and versatile catalyst for alkene, diene, and cycloalkene metathesis](/preview/png/44549.png)
چکیده انگلیسی
A new versatile heterogeneous catalyst for olefin metathesis based on rhenium (VII) oxide supported on organized mesoporous alumina was developed. This catalyst is suitable for metathesis of linear olefins, α-, ω-dienes as well as ring-opening metathesis polymerization of cycloalkenes and cross-metathesis of cycloolefins with linear olefins. This catalyst was found to operate under mild reaction conditions and its activity was much higher than that of corresponding catalyst based on conventional alumina. Catalyst can be used repeatedly and can be easily reactivated. Influence of the catalyst pore size on activity as well as selectivity in individual methathesis reactions was established.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 302, Issue 2, 11 April 2006, Pages 193–200
Journal: Applied Catalysis A: General - Volume 302, Issue 2, 11 April 2006, Pages 193–200
نویسندگان
Roman Hamtil, Naděžda Žilková, Hynek Balcar, Jiří Čejka,