کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4766316 1423898 2017 27 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
3,7-Diaryl substituted 10-butylphenoxazines as new hole transporting materials for organic light emitting devices
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
3,7-Diaryl substituted 10-butylphenoxazines as new hole transporting materials for organic light emitting devices
چکیده انگلیسی
Phenyl, naphthyl or vinylphenyl substituted 10-butylphenoxazines were synthesized by a multi-step synthetic rout. The materials were examined by various techniques including thermogravimetry, differential scanning calorimetry, electron photoemission spectroscopy and time of flight method. The materials were found to show adequate thermal stability having initial thermal degradation temperatures in the range of 280-310 °C. Glass transition temperatures of the low-molar-mass materials were in the rage of 31-65 °C. The electron photoemission spectra of thin layers of the derivatives showed low ionization potentials of 5.1-5.15 eV. Hole drift mobilities in thin layers of some derivatives exceeded 2 × 10−4 cm2V−1s−1 at an electric field of 4 × 105 Vcm−1s at room temperature. These materials have been tested as hole transporting layers in electroluminescent bilayer OLEDs with Alq3 as the emitter. The device with hole transporting layer comprised of 10-butyl-3,7-di(1-naphthyl)phenoxazine exhibited the best overall performance with very low turn-on voltage of 3.6 V, a maximum luminance efficiency of 2 cd/A and maximum brightness of about 7420 cd/m2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 137, February 2017, Pages 208-213
نویسندگان
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