کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4926619 | 1431601 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrogen storage performance of a pseudo-binary Zr-V-Ni Laves phase alloy against gaseous impurities
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
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چکیده انگلیسی
This work illustrates the hydrogen storage performance of Zr(V0.95Ni0.05)2 Laves phase alloy in hydrogen with/without gaseous impurities. It is found that Zr(V0.95Ni0.05)2 can be activated in either pure hydrogen or hydrogen with 1.00Â vol% O2. However, the activation of Zr(V0.95Ni0.05)2 in hydrogen with gaseous impurities requires much more time and higher temperature due to the continually forming passivation layer oxides. Hydrogen storage capacity is found to degrade evidently with increasing oxygen content and the alloy almost loses entire hydrogen absorption capacity in hydrogen with 2.00Â vol% O2. During absorption/desorption cycles, the maximum hydrogen capacity against gaseous impurities decreases in various degree comparing to that in pure hydrogen. At the temperature below 423Â K, the hydrogen desorption capacity decreases gradually with increasing absorption/desorption cycles. The alloys can hardly absorb hydrogen in the third cycle both at 308 and 423Â K. With the further increase of temperature, the hydrogen absorption capacity at the first cycle even shows a little rise at 573Â K comparing with that at 308Â K, indicating a strong temperature dependence of the hydrogen storage degradation against gaseous impurities. Both the kinetics and capacity of Zr(V0.95Ni0.05)2 decrease to a certain extent after 3 absorption/desorption cycles at 723Â K.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Renewable Energy - Volume 103, April 2017, Pages 786-793
Journal: Renewable Energy - Volume 103, April 2017, Pages 786-793
نویسندگان
Tiebang Zhang, Tiandong Wu, Xiangyi Xue, Rui Hu, Hongchao Kou, Jinshan Li,