کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4983621 1454362 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Aqueous boundary lubrication: Molecular mechanisms, design strategy, and terra incognita
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Aqueous boundary lubrication: Molecular mechanisms, design strategy, and terra incognita
چکیده انگلیسی


- Molecular mechanisms of aqueous boundary lubrication lie in hydration lubrication.
- Supramolecular synergy is an area for further investigations.
- The stalk model of membrane fusion may guide molecular designs for boundary layers.
- Structure and morphology of self-assembled surfactant layers remains controversial.
- A new aqueous boundary lubrication regime is proposed for the Stribeck curve.

The molecular mechanisms for aqueous boundary lubrication are very different from those in the classic boundary lubrication, originating from the fluidity of the hydration shells surrounding the surfactant and lipid headgroups. We discuss the important molecular and structural criteria for effective aqueous boundary lubricants, and highlight the strategy for reinforcing the interfacial structure for aqueous boundary lubrication via synergistic interactions between amphiphilic polymers and lipids/surfactants. It is proposed that the energetic considerations of different molecular elastic deformations in the stalk model of cell membrane fusion can be applied to guide our design of molecular architectures for surfactants and lipids to implement structural integrity in aqueous boundary lubrication. We discuss a controversy associated with the quiescent bilayer structure in the context of boundary lubricant interfacial structures. We also highlight other effective aqueous boundary lubrication systems, including hydrated ions and biomimetic hierarchical constructs inspired by the enigmatic and extremely efficient biological lubrication. Finally, we suggest that the Stribeck curve might be re-considered in light of recent advances in aqueous boundary lubrication, although the exact scope of this new aqueous boundary lubrication regime remains terra incognita.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Current Opinion in Colloid & Interface Science - Volume 27, February 2017, Pages 1-8
نویسندگان
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