کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4989513 1456929 2018 25 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation of chloride-free potash fertilizers by electrodialysis metathesis
ترجمه فارسی عنوان
آماده سازی کودهای پتاس حاوی کلرید با استفاده از الکترو دی دیالیز
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
چکیده انگلیسی
Traditional preparation processes of chloride-free potash fertilizers (KNO3, K2CO3 and K2SO4) have certain limitations, such as complicated operation and existing potential pollution. In this work, electrodialysis metathesis (EDM) was used to prepare these fertilizers using KCl and acid radical salt (nitrate, carbonate and sulfate) as raw materials. Firstly, as current density increases from 10 to 25 mA/cm2, energy consumption grows from 0.41 to 0.64 kW h/kg KNO3, while KNO3 product purity improves from 92.36 to 95.91 wt%. Secondly, different sulfate sources, such as MgSO4, Na2SO4 and (NH4)2SO4, were used to investigate the effects of cation species, showing that the orders of energy consumption and impurity cations in product are EMgSO4>ENa2SO4>E(NH4)2SO4 and WNH4>WNa>WMg, and (NH4)2SO4 is regarded as the suitable sulfate source. Thirdly, NaNO3, Na2CO3 and Na2SO4 were selected to investigate the effects of anion species. The order of average energy consumption is E‾K2CO3>E‾K2SO4≈E‾KNO3, while that of average current efficiency is η‾K2SO4>η‾K2CO3>η‾KNO3. Besides, compared with other two fertilizers, generated KNO3 product purity is comparatively higher. Finally, economic evaluation results showed that EDM has great potential applications in preparing chloride-free potash fertilizers, especially for KNO3 and K2CO3.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 191, 31 January 2018, Pages 144-152
نویسندگان
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