کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5009059 | 1462039 | 2017 | 8 صفحه PDF | دانلود رایگان |
- A novel hemicyanine-based ratiometric fluorescent probe 3 for Cu2+ was developed.
- The probe could detect Cu2+ in complete aqueous solution.
- The detection limit of 3 for Cu2+ was found to be 1.1Â nM.
- The probe exhibited a large Stokes shift.
A novel hemicyanine-based ratiometric fluorescent probe 3 for Cu2+ was described. The probe exhibited fluorescence emission at 448Â nm. Upon addition of Cu2+, the emission at 448Â nm quenched and simultaneously generated a significant bathochromic shift of the emission maximum to 503Â nm due to the Cu2+-triggered hydrolysis reaction of the picolinate moiety. Thus, a single-excitation, dual-emission ratiometric measurement with a large red shift in emission (Î55Â nm) and remarkable changes in the ratio (F503nm/F448nm) of the emission intensity (R/R0 up to 22-fold) could be established. Moreover, the probe exhibited a large Stokes shift, high sensitivity (detection limit of 1.1Â nM), and high selectivity for Cu2+ over other metal ions in complete aqueous solution.
693 can detect Cu2+ in complete aqueous solution with ratiometric fluorescence signal output, high sensitivity, and high selectivity over other metal ions.
Journal: Sensors and Actuators B: Chemical - Volume 252, November 2017, Pages 134-141