کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5013098 | 1462830 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Biodiesel production by lipase-catalyzed transesterification of Ocimum basilicum L. (sweet basil) seed oil
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی (عمومی)
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چکیده انگلیسی
The increasing global demand for fuel, limited fossil fuel resources, and increasing concern about the upturn in gaseous CO2 emissions are the key drivers of research and development into sources of renewable liquid transport fuels, such as biodiesel. In the present work, we demonstrate biodiesel production from Ocimum basilicum (sweet basil) seed oil by lipase-catalyzed transesterification. Sweet basil seeds contain 22% oil on a dry weight basis. Artificial neural network with genetic algorithm modelling was used to optimize reaction. Temperature, catalyst concentration, time, and methanol to oil molar ratio were the input factors in the optimization study, while fatty acid methyl ester (FAME) yield was the key model output. FAME composition was determined by gas chromatography mass spectrometry. The optimized transesterification process resulted in a 94.58% FAME yield after reaction at 47 °C for 68 h in the presence of 6% w/w catalyst and a methanol to oil ratio of 10:1. The viscosity, density, calorific value, pour point, and cloud point of the biodiesel derived from sweet basil seed oil conformed to the EN 14214 and ASTM D6751 standard specifications. The antioxidant stability of the biodiesel did not meet these specifications but could be improved via the addition of antioxidant.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Energy Conversion and Management - Volume 132, 15 January 2017, Pages 82-90
Journal: Energy Conversion and Management - Volume 132, 15 January 2017, Pages 82-90
نویسندگان
Zeynab Amini, Hwai Chyuan Ong, Mark D. Harrison, Fitranto Kusumo, Hoora Mazaheri, Zul Ilham,