کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5022355 | 1469488 | 2016 | 23 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Decoration of defect-free graphene nanoplatelets with alumina for thermally conductive and electrically insulating epoxy composites
ترجمه فارسی عنوان
تزئین نانوپلاستیک های گرافن با آلومینا برای کامپوزیت های اپوکسی گرما و رسانا
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی (عمومی)
چکیده انگلیسی
Although graphene can significantly improve the thermal conductivity of polymers due to its high aspect ratio and excellent thermal conductance, it causes serious reduction in electrical insulation and thus limits the wide applications of its polymer composites in the thermal management of electronics and systems. To solve this problem, electrically insulating Al2O3 is used to decorate high quality (defect-free) graphene nanoplatelets (GNPs). Aided by supercritical carbon dioxide (scCO2), numerous Al2O3 nanoparticles are formed on the inert GNP surfaces by fast nucleation and hydrolysis of Al(NO3)3 precursor followed by calcination at 600 °C. Alternatively, by controlling nucleation and hydrolysis of Al2(SO4)3 precursor with a buffer solution, Al2(SO4)3 slowly nucleates and hydrolyzes on GNPs to form aluminum hydroxide, which is then converted to Al2O3 nanolayers without phase separation by calcination. Compared to the Al2O3@GNP hybrid with the assistance of scCO2, the hybrid prepared with the help of a buffer solution is highly efficient in conferring epoxy with excellent thermal conductivity while retaining its electrical insulation. Epoxy composite with 12 wt% of Al2O3@GNP hybrid exhibits a high thermal conductivity of 1.49 W/(mK), which is 677% higher than that of neat epoxy, indicating its high potential as thermally conductive and electrically insulating fillers for polymer-based functional composites.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Science and Technology - Volume 137, 12 December 2016, Pages 16-23
Journal: Composites Science and Technology - Volume 137, 12 December 2016, Pages 16-23
نویسندگان
Renhui Sun, Hua Yao, Hao-Bin Zhang, Yue Li, Yiu-Wing Mai, Zhong-Zhen Yu,