کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5150988 | 1498904 | 2017 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Development of a ruthenium multi-pyridine complex as photosensitizer for highly efficient light driven water oxidation
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Development of a ruthenium multi-pyridine complex as photosensitizer for highly efficient light driven water oxidation Development of a ruthenium multi-pyridine complex as photosensitizer for highly efficient light driven water oxidation](/preview/png/5150988.png)
چکیده انگلیسی
A novel [Ru(bpy)2(tpphz)](PF6)2 complex (PS1) was synthesized and displayed a higher photoactivity than [Ru(bpy)3](PF6)2 and [Ru(bpy)2(dcb)](PF6)2 for water oxidation with Ru(bda)(isoq)2 as catalyst. The main reason for the attractive photocatalytic activity should be that the Ï-Ï stacking supramolecular interaction between the Ï-tpphz ligand of the PS1 and the Ï-isoq ligand of the catalyst increased the intermolecular interaction between PS1 and catalyst, and promoted the molecular aggregation and accelerated valid electronic transmission.159
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 86, December 2017, Pages 10-13
Journal: Inorganic Chemistry Communications - Volume 86, December 2017, Pages 10-13
نویسندگان
Ji Li, Yu Wei, Xu-Yang Chen, Zhi-Liang Zhu, Yan Gao,