Polyoxometalate-induced different metal-organic frameworks based on isonicotinic acid and AgI ion: Syntheses, structures and properties

Two polyoxometalate (POM)-based 3D metal-organic frameworks (POMOFs), [Ag12(INA)8(VW11VIWVO40)(H2O)2]·VO2 (1), {[Ag5(INA)5(HINA)][H3PMo12O40](H2O)}·H2O (2) have been synthesized. Remarkably, a discrete 1D [Ag3(INA)2]n chain and VO2 molecule alternately distribute in the channels of the POMOF 1. The electrochemical and photocatalytic properties of the title complexes have been reported.294